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Potassium hexachlororhodate

potassium hexachlororhodate(iii)

CAS: 13845-07-3

Molecular Formula: Cl6Rh.3K

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Potassium hexachlororhodate - Names and Identifiers

Name potassium hexachlororhodate(iii)
Synonyms Potassium hexachlororhodate
tripotassium hexachlororhodate
Tripotassium hexachlororhodate
Potassium hexachlorohodate(III)
POTASSIUM HEXACHLORORHODATE(III)
potassium hexachlororhodate(iii)
POTASSIUM HEXACHLORORHODIUM (III)
potassium hexachlororhodate(iii), premion
tripotassium,(oc-6-11)-rhodate(3-hexachloro-
Rhodate(3-), hexachloro-, tripotassium, (OC-6-11)-
CAS 13845-07-3
EINECS 237-569-1
InChI InChI=1/6ClH.3K.Rh/h6*1H;;;;/q;;;;;;3*+1;+3/p-6

Potassium hexachlororhodate - Physico-chemical Properties

Molecular FormulaCl6Rh.3K
Molar Mass432.92
Water SolubilitySlightly soluble in cold water, insoluble in alcohol.
Vapor Presure33900mmHg at 25°C
AppearancePowder
Colorred
Exposure LimitACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
Storage ConditionInert atmosphere,Room Temperature
SensitiveHygroscopic
MDLMFCD00192414

Potassium hexachlororhodate - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk Codes36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
WGK Germany3
TSCAYes

Potassium hexachlororhodate - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
Properties Potassium hexachlororrhodium (III) is a red crystalline substance, easily soluble in water and insoluble in ethanol.
introduction potassium hexachlororrhodium (III) is purple-red triclinic crystal or powder. Relative density 3.291. When exposed to water, it decomposes and is slightly soluble in alcohol and potassium chloride. It is prepared by heating rhodium and potassium chloride in a chlorine gas stream or adding potassium chloride to a hot rhodium-containing chlorine ligand. Pure products can be used as analytical standard reagents.
Use Potassium hexachlororrhodium (III) is a metal inorganic salt, which is mainly used as an oxidant.
preparation (1) weigh 5kg of thiourea rhodium waste, and the component analysis results are: n 29.36%, c 19.91%, h 4.54%, s 32.40%, o 10.40% and Rh 0.88%; Place the waste in a stainless steel tray and place it in an incinerator. After closing the furnace door, use nitrogen to clear the air in the furnace, raise the temperature to 600 ℃ and keep the temperature for 40min until no obvious white smoke is generated, I .e. carbonization and decomposition are complete;(2) The black carbide obtained in step (1) is introduced into oxygen-enriched air, and when the temperature drops to room temperature, the incineration residue is taken out to obtain 368.5g residue;(3) After grinding and mixing the residue obtained in step (2) with 370g of potassium chloride, it is transferred to a tubular furnace to raise the temperature to 600 ℃ and feed chlorine gas for reaction, A mixture of potassium hexachlororhodium (III) potassium is obtained.
Last Update:2024-04-10 22:29:15
Potassium hexachlororhodate
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View History
Potassium hexachlororhodate
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